초록 |
Clay minerals are important components of the marine sediments with clathrate hydrates. Most 2:1 clay minerals widespread in the world wide marine and also have many types of clays with different chemical compositions. When the hydrate form between the interlayer of the 2:1 clay minerals, the structure of clays did not change seriously. In this work, we found the experimental proof of the hydrate formation within the the interlayer of 2:1 clay minerals. For the anlaysis of forming hydrate, we used the solid state 13C NMR recorded on a Bruker DMX 400 MHz NMR spectrometer. |