학회 |
한국공업화학회 |
학술대회 |
2006년 봄 (05/12 ~ 05/13, 전북대학교) |
권호 |
10권 1호 |
발표분야 |
촉매 |
제목 |
Microwave synthesis, characterization and catalytic performance of zirconium incorporated SBA-16 |
초록 |
The 3D-cubic Zircornium incorporated SBA-16 mesoporous molecular sieves were directly synthesized under strong acidic condition with microwave method and characterized by various techniques. XRD showed that the synthesized mesoporous materials had a well-ordered cubic structure. UV-Vis result revealed that incorporated Zirconium species had tetrahedral coordination. SEM is used to determine the particle morphology of the synthesized materials. The catalytic test using Meerwein-Ponndorf-Verley reduction of cyclohexanone and bezenealdehyde as a probe reaction proved that the Zr species with tetrahedral coordination in the mesoporous silica matrix showed high activity and almost 100 % selectivity. |
저자 |
강남철, 이종학, 한상철, 박상언
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소속 |
인하대 |
키워드 |
Microwave synthesis; zirconium; SBA-16; mesoporous material; Meerwein-Ponndorf-Verley Reduction
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E-Mail |
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