학회 | 한국화학공학회 |
학술대회 | 2012년 봄 (04/25 ~ 04/27, 제주 ICC) |
권호 | 18권 1호, p.937 |
발표분야 | 재료 |
제목 | Formation of a nanocomposite between mesostructured cellular silica foam and microporous copper trimesate |
초록 | A copper-based MOF(Cu3(BTC)2) was formed in the large pores of a COOH-functionalized mesostructured cellular silica foam (MCF(M)-COOH) leading to hydrophobic nanocomposite. The Cu3(BTC)2 was synthesized with the sequential incorporation of Cu(NO3)2•3H2O and 1,3,5-benzenetricarboxylic acid in a water/ethanol mixture containing the MCF(M)-COOH by microwave irradiation. The nanocomposite was characterized by XRD, BET, FT-IR, TEM and solid state 13C-NMR. The formation of the nanocomposite has increased the sorption rate of hydrophobic hydrocarbon vapour as compared with those of pure Cu3(BTC)2 and MCF(M)-COOH as a result of their hybridization. Reference 1. Y.-K Seo, I. Suryanarayana, Y. K Hwang, N Shin, D.-C A, C.-H Jun and J.-S Chang,. J. Nanosci. Nanotechnol. 2008, 8, 3995. 2. Y.-K Seo, J. W Yoon, U.-H Lee, Y K Hwang, C.-H Jun and J.-S Chang,. Micropore. Mesopre. Mater. in press. |
저자 | 전다혜1, 장종산2, 이지선3, 서유경3, 이우황2 |
소속 | 1과학기술연합대, 2한국화학(연), 3연세대 |
키워드 | |
원문파일 | 초록 보기 |