화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2013년 봄 (04/11 ~ 04/12, 대전컨벤션센터)
권호 38권 1호
발표분야 고분자구조 및 물성
제목 Rheological Properties of poly(vinylidene fluoride)-hexafluoropropylene binder solution: Effects of non-solvent
초록 The Poly(vinylidene fluoride) (PVDF)- Hexafluoropropylene (HFP) /polyolefin separators are prepared by a dip-coating process with various compositions of PVDF and HFP, in which acetone as a solvent is used to dissolve different commercial PVDF-HFP binders and to make their slurries. PVDF-HFP/polyolefin separator is obtained by spreading the slurry on the surface of the polyolefin film. Phase transition occurred in the binder slurry by adding water as a non-solvent, in which process the binder was tightly adhered on to a polyolefin film after drying process. The object of this study we investigated effect of non-solvent on the phase transition of different PVDF-HFP binder solutions using a rotational rheometer. However, Addition of water result in phase transition rapidly. They cannot be measured rotational rheometer. In this study, instead of water, we used methanol as non-solvents.
저자 권승혁, 최형진
소속 인하대
키워드 Lithium-ion batteries; Separators; Ceramic coating; Phase inversion; Non-solvent
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