화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2008년 가을 (10/23 ~ 10/24, 부산 BEXCO)
권호 14권 2호, p.3548
발표분야 촉매 및 반응공학
제목 Toluene oxidation over the perovskite-type metal oxide prepared by using mesoporous silica
초록 Perovskite-type oxides have high potential in various oxidations. The perovskite-type oxides prepared by the classical methods have low surface area due to high calcination temperature for forming the perovskite structure.
A new synthesis route using mesoporous silica as a host was investigated to produce perovskite-type oxide with high surface area. It was characterized with XRD, N2-adsorption/desorption, EDX and TEM. The perovskite-type oxide prepared by the new synthesis using the mesoporous silica showed the crystallite size of 7 nm and the surface area of 140 m2/g. The small crystallite size was caused by forming the perovskite-type oxides of metal precursors inside mesopores of silica. The perovskite-type oxide prepared by the new synthesis using the mesoporous silica showed higher activity in the toluene total oxidation than those prepared by classical methods.
저자 서명지, 임선기
소속 KAIST
키워드 perovskite; catalyst; mesoporous; toluene
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