화학공학소재연구정보센터
학회 한국재료학회
학술대회 2012년 가을 (11/07 ~ 11/09, 라카이샌드파인 리조트)
권호 18권 2호
발표분야 C. 에너지/환경 재료(Energy and Environmental Materials)
제목 Studies on the effects of pre-treatment conditions on the properties of the CuInS2 (CIS) absorber thin films
초록 CuInS2 (CIS) absorber thin films were prepared on soda lime glass substrates by sulfuriztion of sputtering deposited stacked Cu/In precursor thin films. The Cu-In precursor thin films were sulfurized in the mixture of H2S (5 %) + N2 (95 %) atmosphere with different post-annealing steps. The effect of different post-annealing steps such as holding times and increasing rates on the structural, compositional, chemical binding energy, optical and electrical properties of the CIS thin films were studied using FE-SEM (field-emission scanning electron microscopy), XRD (X-ray diffraction), EDS (energy dispersive spectroscopy), Raman spectroscopy, Hall measurement, respectively. The XRD, Raman, FE-SEM, Hall measurement and UV-vis results indicated that the properties of sulfurized CIS thin films were strongly related to the post-annealing steps. In particular, the microstructures of the sulfurized CIS thin films were denser without voids using post-annealing process as compared to that without post-annealing process. Further detailed analysis and discussion for effect of post-annealing steps on the properties CIS thin films will be discussed.
저자 강명길1, 신승욱2, 한준희2, 윤재호3, 문종하1, 이정용2, 김진혁1
소속 1전남대, 2한국과학기술원 신소재공학과, 3한국에너지기술(연)
키워드 CuInS2 (CIS); sulfurization process; post-annealing; thin film solar cells; post-annealing process
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