화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2002년 가을 (10/11 ~ 10/12, 군산대학교)
권호 27권 2호, p.165
발표분야 기능성 고분자
제목 Proton conducting Composite Membranes Derived from Sulfonated Polyhydrocarbon and Inorganic Materials
초록 The electrolyte in PEMFC (Polymer Electrolyte Membrane Fuel Cell) is a membrane (fluorinated sulfonic acid polymer or other similar polymer) that is an excellent proton conductor. The perfluorinated ionomers have an outstanding chemical stability and excellent performance in fuel cell application. But their main shortcomings of these materials are their high price, toxic production process and methanol cross-over in direct methanol fuel cells (DMFC). In this research, we synthesized polymer electrolyte membranes based on PEEK(poly ether ether ketone) and inorganic material composite and characterized their thermal, chemical, electrochemical properties by IEC, TGA, SEM, FRA etc. These composite membranes show 10-3 S/cm proton conductivity, 30-40% water uptake, low methanol permeability and 1.6 meq/g IEC (Ion Exchange Capacity).
저자 장재혁1, 박오옥2, 김창수*
소속 1카이스트 생명화학공학과, 2*한국에너지기술(연)
키워드 T
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