화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2013년 가을 (10/11 ~ 10/12, 창원컨벤션센터)
권호 38권 2호
발표분야 분자전자 부문위원회
제목 Electrical Transport through Single Nanowires of Dialkyl Perylene Diimide
초록 We investigated charge transport through individual single-crystalline PTCDI-C5 and PTCDI-C8 nanowires prepared by a solution-phase self-assembly method. Temperature-dependent mobility measurements revealed distinct transport characteristics in the two types of nanowires. The PTCDI-C8 nanowire having shorter intermolecular distances exhibited a transition in the electrical transport from a thermally activated process to a band-like transport with increasing temperature. In contrast, the transport through the PTCDI-C5 nanowire was mostly determined by thermally activated behavior. The observation of band-like transport in the PTCDI-C8 nanowire was attributed to the small number of charge traps. Meanwhile, band-like transport was hardly attainable in the PTCDI-C5 nanowire due to the presence of a large number of charge traps. Unlike the case of the single-crystal PTCDI-C8 nanowire, thin films of PTCDI-C8 contained significant numbers of exponentially distributed charge traps.
저자 김범준1, 유호정2, 오준학2, 강문성3, 조정호1
소속 1성균관대, 2울산과학기술대, 3숭실대
키워드 organic semiconductor; single crystal; solution-phase self-assembly; band-like transport; field-effect transistors
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