학회 |
한국공업화학회 |
학술대회 |
2018년 봄 (05/02 ~ 05/04, 대구 엑스코(EXCO)) |
권호 |
22권 1호 |
발표분야 |
석유화학윤활유_포스터 |
제목 |
Effects of the Hydrocracking Catalyst and Deoxygenation/Hydrocracking Steps for Maximizing Biojet Fuel Production from Triglyceride |
초록 |
Various parameters in the catalytic hydroconversion of triglycerides were investigated for maximizing the production of biojet fuel. The results demonstrated that the two-step reaction process (separate hydrotreating/hydrocracking steps) is more advantageous than the single-step direct hydrocracking process in terms of high biojet fuel yield, suppressed production of aromatic compounds, and long catalyst lifetime. In the two-step process, the diffusion characteristics of the multibranched hydrocarbon in the hydrocracking catalysts could be correlated with the biojet fuel yields and the iso/n-paraffin ratios in biojet fuel. Consequently, Pt supported on nanocrystalline large-pore BEA zeolite produced the largest biojet fuel yield with highest iso-paraffin content as a result of suppressed overcracking. Under the optimized conditions, 55 wt% of biojet fuel with respect to palm oil was achieved after final distillation, which satisfied all the required fuel specifications. |
저자 |
김명엽1, 김재곤2, 이미은2, 이송현1, 최민기1
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소속 |
1한국과학기술원, 2한국석유관리원 |
키워드 |
Biojet Fuel; Hydrocracking; Zeolite
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E-Mail |
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