| 학회 |
한국공업화학회 |
| 학술대회 |
2012년 가을 (10/31 ~ 11/02, 대전컨벤션센터) |
| 권호 |
16권 2호 |
| 발표분야 |
포스터-고분자 |
| 제목 |
Synthesis of Poly(Trifluoroethylene-co-Hexafluoropropylene) |
| 초록 |
Polytrifluoroethylene (PTrFE) and its copolymer with hexafluoropropylene (HFP) were successfully prepared from free radical suspension polymerizations using diisopropyl peroxidicarbonate (DIPPDC) in presence of 1,1,2-trichlorotrifluoroethane (CFC-113) The reactivity ratios of TrFE and HFP were estimated as rTrFE=5.6±1.19 and rHFP≈0. This results indicate that HFP cannot undergo self propagation. The weight average molecular weight and yield of copolymers were found to decrease with increasing HFP content. On the other hand, the molecular weight distribution became increasingly narrow. Melting temperature and glass transition temperature of copolymers linearly decreased with increase of HFP content. |
| 저자 |
이상구1, 하종욱1, 박인준1, 이수복1, 이종대2
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| 소속 |
1한국화학(연), 2충북대 |
| 키워드 |
trifluoroethylene; hexafluoropropylene; reactivity ratio
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| E-Mail |
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