| 학회 |
한국고분자학회 |
| 학술대회 |
2011년 가을 (10/06 ~ 10/07, 김대중 컨벤션센터) |
| 권호 |
36권 2호 |
| 발표분야 |
고분자합성-구조제어중합 |
| 제목 |
Synthesis of Electro-optical Poly(thiophene/3,4-ethylenedioxythiophene) Core/shell Nanocomposites using Two Step Fe3+- catalyzed Oxidative Polymerization |
| 초록 |
Poly(thiophene/3,4-ethylenedioxy thiophene) core/shell nanocomposites were prepared using poly(styrene sulfonate) (PSS) as a polymeric surfactant by two step Fe3+-catalyzed oxidative polymerization in aqueous medium. The particle size of poly(Th/EDOT) core/shell nanocomposites dispersions was analysed by capillary hydrodynamic fractionation(CHDF). The morphology of poly(Th/EDOT) core/shell nanocomposites was observed by scanning electron microscope(SEM) and transmission electron microscopy(TEM), proving the core/shell structure of nanocomposites. The electrical properties of nanocomposites were investigated using 4-point probe method. Also the optical property and thermal stability of the nanocomposites were measured by photoluminescence spectroscopy(PL) and thermogravimetric analysis(TGA). Poly(Th/EDOT) core/shell nanocomposites can be applying to electrical devices such as electrostatic discharge, solar cell, OLED and transistor. |
| 저자 |
이승환, 이선종, 박홍관, 이승모, 류현욱, 김인영, 유도혁, 김중현
|
| 소속 |
연세대 |
| 키워드 |
Oxidative polymerization; poly(Th/EDOT); core/shell nanocomposites; electro-optical property.
|
| E-Mail |
|
