| 초록 |
Typical colloidal particles attach to fluid-fluid interfaces owing to the reduction of surface free energy. The particles located at an oil-water interface experience two competitive interactions; one is the capillary interaction due to the interface deformation and the other is the electrostatic interaction cause by the asymmetric surface charge distribution on the particles. When spherical particles reside at the oil-water interface, they exhibit abnormally strong electrostatic repulsions that decay as r-4, where r is the center-to-center separation between the particles. In contrast, for geometrically anisotropic particles, the capillary interaction becomes dominant, compared to the electrostatics. Furthermore, we clarify the effect of particle configurations with respect to the interface on the interaction magnitude and equilibrium microstructures. |
