| 초록 |
The fine tuning of the dominant polarity in polymer semiconductors is a key issue for high-performance organic complementary circuits. In this paper, we demonstrate a new methodology for addressing this issue in terms of molecular design. In an alternating conjugated donor−acceptor copolymer system, we systematically engineered the chemical linkages that connect the aromatic units in donor moieties. As a result, the polarity balance, which is quantified as the electron/hole mobility ratio, was dramatically tuned from 0.01 to 2.7. Our finding demonstrates a new methodology for the molecular design of highperformance organic complementary circuits. |
