화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2012년 봄 (04/12 ~ 04/13, 대전컨벤션센터)
권호 37권 1호
발표분야 고분자구조 및 물성
제목 Phase separation of a liquid crystal/diacrylate monomer mixture induced by photo-polymerization in a microfluidic channel
초록 A microfluidics chip was used with UV exposure for making functional particles using a tripropane glycol diacrylate(TPGDA)/4-cyano-4’-pentylbiphenyl(5CB) mixture with photoinitiator as the disperse phase and water as the continuous phase. The oil in water droplets were successfully made in the microfluidics channel with a narrow size-dispersity. The initial homogenous droplet was phase-separated into the two-phase droplet by UV exposure. The core and shell in the two-phase droplet were 5CB-rich and poly(TPGDA)-rich, respectively. The phase-separated droplets were easily observed from an optical microscope with crossed polarizers. The effect of the concentration of the photo-initiator and the mixture ratio was explored in this study. The various-shape droplets including vesicles and porous sphere could be produced after removing 5CB in ethanol from the phase-separated droplet. This facile method may be applied to many fields such as drug delivery and ink-jet systems
저자 김지연, 박수영
소속 경북대
키워드 microfluidic; droplet; TPGDA; 5CB
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