화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2010년 봄 (04/08 ~ 04/09, 대전컨벤션센터)
권호 35권 1호
발표분야 대학원생 구두발표
제목 Ultrahigh density Arrays of Poly (3-hexylthiophene) Nanotube with Enhanced Chain Orientation
초록 Poly (3-hexylthiophene, P3HT), representative of conjugated polymers, has been extensively investigated due to its electrical properties, stability, and solution-processability applicable to organic field-effect transistors, chemical sensors, and photovoltaic solar cells. As electronic elements, simultaneous control of nanoscale morphology and chain alignment has been critical issue because of anisotropic charge transport in conjugated polymers. Here, we fabricated ultrahigh density arrays of P3HT nanotube via solution wetting in nanoporous template. It is found that the P3HT nanotube array has enhanced (010) planar structure due to π-π interchain stacking perpendicular to the substrate. As a result of this enhanced molecular ordering, the conductivity was higher about 8 times than that of the continuous film.
저자 변진석, 김영석, 전금혜, 김진곤
소속 포항공과대
키워드 P3HT; Nanotube; Chain orientation; Conductivity
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