| 초록 |
In this research, we report new MOF UTSA-16 (Zn) synthesized with the help of microwave irradiation for CO2 capture. The synthesis procedure was inspected by changing synthesis time to determine a finest time for the UTSA-16 (Zn) formation. In our previous study we found that in as synthesis reaction time increases particle size of MOF UTSA-16 decreases but, in this study no significant difference in particle size was found as synthesis reaction time increases. The CO2 and N2 adsorption capacities as well as selectivities were measured by using a volumetric method and compared to detect the synthesis time dependence on the adsorption performance. The synthesized samples with different reaction times were characterized to identify crystal structure, surface area, particle size, and thermal stability by using XRD, BET, SEM, and TGA respectively. |
