| 학회 | 한국공업화학회 |
| 학술대회 | 2007년 봄 (05/11 ~ 05/12, 계명대학교) |
| 권호 | 11권 1호 |
| 발표분야 | 정밀화학 |
| 제목 | 균일계 촉매를 이용한 ester의 hydrofomylation 반응 |
| 초록 | The hydroformylation reaction of the α,β-unsaturated esters, methyl acrylate, methyl methacrylate, and α-methylene-γbutyrolactone were carried out at 50 - 130 oC under 600 psi of synthesis gas (CO/H2 = 1/1) using zwitterionic, cationic, and neutral rhodium(Ⅰ) complexes as catalyst precursors, in the presence or absence of dppb. Rh(cod)(η6-PhBPh3), [Rh(cod)(dppb)]+BF4-, and [Rh(cod)Cl]2 were used as the zwitterionic, cationic, and neutral rhodium complexes, respectively. |
| 저자 | 이철우, 이원묵 |
| 소속 | 한밭대 |
| 키워드 | hydroformylation; Rh catalyst; unsaturated ester |
