화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2014년 가을 (10/22 ~ 10/24, 대전 DCC)
권호 20권 2호, p.1627
발표분야 에너지
제목 Influence of pH on the hydrothermal conversion of macroalgae-derived sodium alginate into organic acids under subcritical water conditions
초록 The hydrothermal treatment of sodium alginate was conducted in subcritical water as a function of pH in order to investigate the effects of catalysts on alginate depolymerisation and organic acid production. At pH 1, the acid-catalysed hydrothermal decomposition of alginate promoted the production of monomers (mannuronic acid and guluronic acid) and glycolic acid. On the other hand, at pH 13, the lactic acid and dicarboxylic acids (malic acid and fumaric acid) were predominantly produced by the base-catalysed reaction. Regardless of the presence of catalysts, increasing the reaction temperature enhanced both the acid- and base-catalysed reactions via changes in properties of subcritical water. Our study demonstrates that optimizing the reaction conditions (temperature, time and pH) is important for the efficient conversion of seaweed-derived biomass into value-added organic acids.
저자 전원진1, 반충현1, 박건우1, 유태경1, 서정용1, 우희철2, 김도희1
소속 1서울대, 2부경대
키워드 Marine biomass; Alginate; Hydrothermal conversion; Organic acids
E-Mail
원문파일 초록 보기