| 학회 |
한국공업화학회 |
| 학술대회 |
2018년 봄 (05/02 ~ 05/04, 대구 엑스코(EXCO)) |
| 권호 |
22권 1호 |
| 발표분야 |
고분자_포스터 |
| 제목 |
Lignin Based Solid Polymer Electrolytes for All-Solid-State Lithium-Ion Battery |
| 초록 |
A series of lignin based copolymers were synthesized and used as solid polymer electrolytes (SPEs) for lithium secondary batteries. Star shaped poly(poly(ethylene glycol) methyl ether methacrylate-co-glycidyl methacrylate)(PEGMA-co-GMA) having lignin core was synthesized via atom transfer radical polymerization (ATRP) and crosslinked using photo acid catalyst. Physical, morphological and electrochemical properties of SPEs were systematically analyzed. The ionic conductivity of synthesized polymers are increased as the composition of PEGMA increased. When the molar ratio of PEGMA to GMA was 95:5, free standing film with the highest ionic conductivity was obtained. In addition, superior electrochemical performance was obtained when a star shaped polymer synthesized by ATRP with lignin core was used as a binder instead of PVDF. |
| 저자 |
정다운1, 심지민2, 이종찬1
|
| 소속 |
1서울대, 2Univ. of Minnesota |
| 키워드 |
Lignin; Solid polymer electrolyte; lithium-ion battery
|
| E-Mail |
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