| 학회 |
한국고분자학회 |
| 학술대회 |
2002년 봄 (04/12 ~ 04/13, 서울대학교) |
| 권호 |
27권 1호, p.81 |
| 발표분야 |
고분자 합성 |
| 제목 |
Conjugated Ionic Polymer with Side-Chain Liquid Crystalline Moieties |
| 초록 |
Conjugated ionic polymer system from acetylene derivatives have potential as materials for mixed ionic and electronic conductivity, energy storage devices such as batteries and permselective membrane, and light-emitting devices, due to the their extensive conjugation and various functionalities. The conjugated ionic polymer with liquid crystalline (LC) moiety was prepared by the activated polymerization of 2-ethynylpyridine using the LC-alkyl bromide at elevated polymerization temperature. The color of the reaction solution changed from light brown of the initial mixture of 2-ethynylpyridine and LC alkyl bromide into dark black. The polymer structure of the resulting polymer was characterized by elemental analysis, NMR, infrared, and UV-visible spectroscopies. The polymers were completely soluble in DMF, DMSO. N,N-dimethylacetamide, formic acid, etc. The photoluminescence peak is located at 430 and 454 nm corresponding to the photon energy of 2.8 and 2.66 eV. |
| 저자 |
제갈영순1, 진성호*2, 박종욱**3, 이원철***4, 안원술****5, 고광락*****6, 김성훈******7
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| 소속 |
1경일대, 2*부산대, 3**충주대, 4***경일대, 5****계명대, 6*****경북대, 7******경북대 |
| 키워드 |
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| E-Mail |
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