| 학회 |
한국공업화학회 |
| 학술대회 |
2005년 가을 (10/28 ~ 10/29, 건국대학교) |
| 권호 |
9권 2호 |
| 발표분야 |
우수논문(대학원우수논문) |
| 제목 |
UV Direct Photolysis of 2,2'-Azino-bis(3-ethylbenzothiazoline-6-sulfonate) (ABTS) in Aqueous Solution: Application as a Novel Chemical Actinometer |
| 초록 |
The direct photolysis of 2,2'-azino-bis(3-ethylbenzothiazoline-6-sulfonate) (ABTS) in aqueous solution was investigated under ultraviolet (UV) irradiation. It was newly found that ABTS is directly photolyzed to yield the one-electron oxidized radical, ABTS∙+, which is a blue-green colored persistent radical species with strong visible absorption bands. The photochemical production of ABTS∙+ was strongly dependent on the solution pH and the presence of dissolved oxygen. From the observed photolytic behaviors, the possible mechanisms of ABTS photolysis were proposed. The proposed photolytic reactions were supported by the observed stoichiometry between the amounts of ABTS∙+ radicals produced and ABTS molecules decomposed. |
| 저자 |
이창하, 조민, 윤제용
|
| 소속 |
서울대 |
| 키워드 |
ABTS; photolysis; actinometer
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| E-Mail |
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