화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2017년 가을 (10/11 ~ 10/13, 제주컨벤션센터)
권호 42권 2호
발표분야 고분자구조 및 물성
제목 Nafion-assisted liquid phase exfoliation of MoS2 and its application in Hydrogen Evolution Reaction
초록 Solvent-assisted exfoliation method is one of the simplest methods for exfoliation of layered materials. Among the various solvents, water is not toxic and has a relatively low boiling point, which is considered to be an ideal solvent for liquid phase separation. However, because of the hydrophobic nature of TMDs, there is a problem that the dispersibility is very poor in hydrophilic water. In this study, bulk MoS2 is exfoliated in nafion-assisted water and then apply exfoliated MoS2 nanosheet to HER catalysis, because nafion is an essential additive to the HER test as a binder. Interestingly, it can be seen that there is a difference in the dispersibility and the exfoliation yield depending on the nafion addition volume. Through nafion-assisted water phase exfoliation method, it can be identify that nafion have a feasibility to use in exfoliation of layered materials and good potentials in various promising applications, such as energy conversion and storage without removing.
저자 오남근1, 이훈주2, 김웅수2, 서지형2, 이정현2, 신현석2, 박혜성2
소속 1울산과학기술원, 2UNIST
키워드 MoS2; liquid phase exfoliation; nafion; HER; dispersibility; amphiphilic; non-covalent bonding
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