화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2013년 봄 (04/11 ~ 04/12, 대전컨벤션센터)
권호 38권 1호
발표분야 분자전자 부문위원회
제목 Spontaneous Phase Separation of Zinc Oxide (ZnO) Interfacial Layer in Bulk Heterojunction Polymer Solar Cells
초록 The interfacial layers in Polymer solar cells (PSCs) are necessary for high performance because it is useful to match the energy level between electrode and active layer. Thus the multiple structures of PSCs are required, however, these structures are not favorable to roll-to-roll processes and need additional cost of production. In this study, the active layer and electron transport layer (ETL) were simultaneously deposited with vertical phase separation. The zinc oxide (ZnO) was selected as ETL. The zinc acetate solutions were mixed in blended active solution of poly(3-hexylthiophene (P3HT) and [6,6]-phenyl-C61-butyric acid methyl ester (PCBM). To analyze the phase separation, atomic force measurement, secondary ion mass spectroscopy and contact angle were measured. These results showed that the zinc atoms were vertically phase-separated due to difference of surface energy and density. These devices had similar performance compare to the device made by conventional method.
저자 정은숙, 유병관, 여준석, 김동유
소속 광주과학기술원
키워드 zinc oxide; phase separation
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