화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2002년 가을 (10/24 ~ 10/26, 서울대학교)
권호 8권 2호, p.2705
발표분야 촉매/반응공학
제목 티타니아/유리섬유를 이용한 톨루엔 광촉매 분해반응에서 티타니아의 활성저하와 재생
초록 Two titania photocatalyst supported on glass fiber (GF) were prepared using anatase-type crystalline P25 powder and dilute titanium isoporpoxide solution (DTS) in ethanol. Although a large amount of titania was stably impregnated on glass fiber on the DTS/GF catalyst, low-temperature calcinations brought about a partial reduction of titanium atoms and heavy deposit of carbonaceous materials. Both the catalysts were active in the photocatalytic degradation, while deactivation by the accumulation of reactant and carbonaceous material was observed. Hydrogen peroxide regenerated completely deactivated P25/GF catalyst by removing contaminants, but enhanced the activity of the used DTS/GF catalyst better than the fresh one by increasing the surface concentration of active oxidizing species as well as removing carbonaceous materials.
저자 유영산, 정경환, 김영만, 김종호, 서곤
소속 전남대
키워드 Deactivation; Regeneration; TiO2; H2O2; XPS
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