| 학회 |
한국공업화학회 |
| 학술대회 |
2008년 가을 (11/12 ~ 11/14, ICC 제주) |
| 권호 |
12권 2호 |
| 발표분야 |
촉매 |
| 제목 |
Chemical degradation of the PCBs-contaminatied soilds |
| 초록 |
The chemical degradation of PCBs in soil was carried out in the presence of methanol, 4,4’-Dipyridyl, Fe3+ and H2O2. The PCB mixtures could successfully be transformed into CO2and Cl-, andthe degradation reaction was suggested to occur with hydroxyl radical(OH). The hydroxyl radical was believed to be formed from the reaction of H2O2 with Fe2+ which had been reduced from Fe3+ by the charge transfer between methanol and 4,4’-Dipyridyl. The hydroxyl radical-induced PCBs degradation was composed of two sequential steps, that is, the dechlorination and the oxidation of the dechlorinated intermediates into carbon dioxide. The produced dechlorinated intermediates were proposed to be oxidized completely and very quickly. |
| 저자 |
김둘선, 김성진, 김태한, 조미정, 레넥투안, 이동근
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| 소속 |
경상대 |
| 키워드 |
PCB; dechlorination; chemical degradation
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| E-Mail |
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