화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2007년 가을 (10/11 ~ 10/12, 일산킨텍스)
권호 32권 2호
발표분야 분자전자 소재 및 소자 기술(분자전자 부문위원회)
제목 Preparation and Device Application of Novel Bithiazole-containing Conjugated Polymers
초록 Conjugated polymers have gained much research interest due to their potentialities of flexible/printable electronics. We report here the synthesis via Suzuki polymerization of novel alternating polymers containing 9,9-dioctylfluorene and electron-withdrawing bithiazole moieties, and their application to electronic devices. The UV-vis. absorption and PL emission spectra of the polymers were measured to investigate their optical properties. Cyclic voltammetry experiment showed the improvement of n-doping stability of the polymers as well as the decrease of their LUMO energy levels as a result of bithiazole in the polymer main-chain. Conventional PLED devices were fabricated using the polymers as emitting layers, and EL emission colors were tuned from green to red by thiophene ring extension of the monomer. In addition, an organic solar cell device and an organic thin-film transistor making use of the polymers were also fabricated and characterized.
저자 이재민1, 윤성철1, 임종선1, 김동욱1, 강영구1, 한미정1, 이창진1, 심홍구2
소속 1한국화학(연), 2한국과학기술원 화학과
키워드 Conjugated polymer; bithiazole
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