화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2015년 가을 (10/06 ~ 10/08, 대구컨벤션센터(EXCO))
권호 40권 2호
발표분야 고분자합성
제목 Soluble Aromatic Polyamides from Asymmetric Diamine with Two Trifluoromethyl Groups
초록 Aromatic polyamides(PA) are widely used as a high-performance polymer in advanced technologies due to their outstanding thermal and mechanical properties. Nevertheless, PAs have a problem like poor solubility in most organic solvents, leading to limitation on their application. To overcome this problem, many research efforts have been made to enhance its solubility by introducing bulky pendant groups or flexible linkage into polymer backbone. Ether linkage which can be considered as a flexible linkage offers enhanced solubility, color, and melt-processing properties. In addition, incorporation of CF3 pendant groups can be an effective means to improve the polymer solubility without deteriorating their properties. In this study, we designed asymmetrical diamine monomer containing ether and CF3 groups as a linkage and pendant moieties, respectively, and synthesized a series of PAs from the monomer. The synthesis and characterization of the PAs will be presented
저자 김상율1, 정임식2, 김선달3, 변태준1
소속 1KAIST, 2KRIBB, 3국방과학(연)
키워드 Aromatic polyamides; trifluoromethyl group
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