| 학회 |
한국고분자학회 |
| 학술대회 |
2010년 봄 (04/08 ~ 04/09, 대전컨벤션센터) |
| 권호 |
35권 1호 |
| 발표분야 |
고분자 구조 및 물성 |
| 제목 |
Supramolecular Design from MOF to Processible Metallo-polymers |
| 초록 |
A novel design strategy that extends the metal-organic frameworks (MOFs) into tractable metallo-polymers was successfully explored by incorporating a homologous series of alkyl side chains with various lengths (the number of methylene unit, n = 6~14) to an organic linker, in which the length of alkyl side chain could be key factor to lead to either IRMOF or layered structured polymers. Additionally, this system shows the drastic solid-to-solid transformation from IRMOF to layered polymer according to the lengths of alkyl side chain (n = 8, 9). This transformation is attributed to the contribution of the self-layering ability of long alkyl side chain and volume stress due to the occupancy of side alkyl chain within pores. |
| 저자 |
최은영, 이석현, 고춘길, 이홍준, 홍은영, 정찬근, 김필주, 권오필
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| 소속 |
아주대 |
| 키워드 |
Metallo-polymer; metal organic framework; transformation
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| E-Mail |
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