| 학회 |
한국고분자학회 |
| 학술대회 |
2010년 가을 (10/07 ~ 10/08, 대구 EXCO) |
| 권호 |
35권 2호 |
| 발표분야 |
고분자 합성 |
| 제목 |
Synthesis and self-assembly of semifluorinated block copolymers by solvent induced phase separation method |
| 초록 |
Amphiphilic block copolymers of poly(ethylene oxide) and poly(1H,1H-dihydro perfluorooctyl methacrylate) (PEO-b-PFOMA) were synthesised by atom transfer radical polymerization of fluorooctyl methacrylate using PEO macroinitiators. The PEO-Br macroinitiator was prepared by chemical modification of hydroxy terminated PEO. The structures and molecular characteristics of the PEO-b-PFOMA block copolymers were studied by 1H-NMR and GPC. Transmission electron microscopy (TEM) was used to investigate the surface morphology of the block copolymers. The development of the morphology of PEO-b-PFOMA block copolymers was also investigated after annealing in solvent vapor to get well-order spherical morphology. |
| 저자 |
안, Harun, 임권택
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| 소속 |
부경대 |
| 키워드 |
Amphiphilic block copolymer; solvent vapor; phase separate
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| E-Mail |
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