| 학회 |
한국공업화학회 |
| 학술대회 |
2018년 가을 (10/31 ~ 11/02, 제주국제컨벤션센터(ICC JEJU)) |
| 권호 |
22권 2호 |
| 발표분야 |
환경.에너지_포스터 |
| 제목 |
Mechanistic Study on Selective Aerobic Oxidation of Sulfur Mustard Simulant |
| 초록 |
A new metal-free catalytic reaction system of tribromide and nitrate is designed to selectively oxidize 2-chloroethyl ethyl sulfide (CEES), a simulant of sulfur mustard, into 2-chloroethyl ethyl sulfoxide (CEESO). The system exhibits a high catalytic activity at ambient conditions without addition of any mineral or organic acid, which is commonly used in most other metal-free catalytic systems. A detailed mechanistic study reveals that tribromide plays a key role in the formation of bromosulfonium reactive intermediate and nitrate is further involved in the oxidation of the intermediate to produce final product. A fundamental kinetic model fully describing the overall reaction behaviors of CEES oxidation and the buildup of open catalytic loop is developed. In this presentation, mechanistic modeling and engineering strategies will be extensively discussed for the efficient design of reacting systems for selective sulfoxidation. |
| 저자 |
Ngan Hong Le1, 조정모1, 변아름1, 한요한1, 류삼곤2, 정현숙2, 박명규2
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| 소속 |
1한국화학(연), 2국방과학(연) |
| 키워드 |
Sulfoxidation; Sulfur Mustard; Mechanistic Study
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| E-Mail |
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