| 학회 |
한국화학공학회 |
| 학술대회 |
2006년 가을 (10/27 ~ 10/28, 고려대학교) |
| 권호 |
12권 2호, p.2558 |
| 발표분야 |
촉매 및 반응공학 |
| 제목 |
Mediated Electrochemical Oxidation Process: Determination of Rate Constants for the Destruction of Phenol in Batch and Continuous Feeding Modes |
| 초록 |
The mediated electrochemical oxidation (MEO) process was employed for the destruction of phenol in batch and continuous modes. Cerium(IV) was used as an oxidant in nitric acid medium. In all cases almost 95 % destruction efficiency was achieved both in terms of CO2 and TOC analyses. The rate constant values were calculated for all phenol during the batch and in continuous process of organic addition. In case of continuous organic feeding mode the rate constant was calculated based on a simple mathematical procedure. The rate constants obtained from batch reaction shows the existence of two different kinetic regimes. The rate constants obtained from the model fitting was explained to be the average of the two kinetically different processes. |
| 저자 |
발라지, 정상준, 문일식
|
| 소속 |
순천대 |
| 키워드 |
MEO; Phenol; Ce(IV); Destruction
|
| E-Mail |
|
| VOD |
VOD 보기 |
| 원문파일 |
초록 보기 |
