| 학회 | 한국공업화학회 |
| 학술대회 | 2022년 봄 (05/11 ~ 05/13, 제주국제컨벤션센터(ICC JEJU)) |
| 권호 | 26권 1호 |
| 발표분야 | 포스터-전기화학 |
| 제목 | C-C coupling on CuP2 electrocatalyst reduce CO2 to multi-carbon fuel: Steering selectivity to 1-butanol |
| 초록 | Electrochemical method for reduction of carbon dioxide (CO2) convert into valuable organic compounds, is a great solution to solve the problem of CO2 accumulation. [1],[2] In our previous study, the generation of 1-butanol from carbon dioxide (CO2) on a phosphorus-rich copper cathode was first reported.[3] The faradaic efficiency of the obtained formate and acetaldehyde intermediates led us to propose a mechanism for the formation of 1-butanol that does not include a *CO dimerization step. 13C labeling experiments confirmed that the origin of each product was from dissolved CO2. This study provides a perspective on the C–C coupling reaction on Cu-based electrocatalysts for the electroreduction of CO2 into high-value multicarbon products. [1] Catalysis today, 355, 340-346 (2020) [2] The Chemical Record, 20, 89-101 (2020) [3] ACS Energy Letters, 6, 2090-2095 (2021) [4] Chemical Engineering Journal, 430, 132563 (2022) |
| 저자 | 최민준, 이재영 |
| 소속 | 광주과학기술원 |
| 키워드 | CO2 reduction; C-C coupling; 1-butanol |
