| 학회 |
한국고분자학회 |
| 학술대회 |
2012년 가을 (10/11 ~ 10/12, 창원컨벤션센터) |
| 권호 |
37권 2호 |
| 발표분야 |
분자전자 부문위원회 |
| 제목 |
Synthesis and characterization of low band gap polymers based on strong acceptor for organic photovoltaic cells and organic thin film transistors |
| 초록 |
We synthesized monomers through alkylation, lithiation and bromination. And polymers prepared by the Stille cross-coupling polymerization. The obtained polymers were soluble in common organic solvents such as THF, toluene, chloroform, and chlorobenzene. The structure of copolymers was confirmed by H NMR. Molecular weight of ploymers were obtained by using GPC. These polymers decomposition temperature are over 300oC as measured using thermogravimetric analysis. The photophysical properties for polymers were investigated by UV (ultraviolet spectrum). Highest occupied molecular orbital (HOMO) energy levels and Lowest Unoccupied Molecular Orbital (LUMO) was estimated by CV (cyclic voltammetry). A series of donor-acceptor alternative colopymers were designed and synthesized to investgate the performance on thin film transistor properties and photovoltaic properties of conjugated polymers. |
| 저자 |
황문찬, 박소민, 하종진, 김슬옹, 권순기, 김윤희
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| 소속 |
경상대 |
| 키워드 |
OPV; OTFT
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| E-Mail |
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