| 학회 |
한국공업화학회 |
| 학술대회 |
2015년 가을 (11/04 ~ 11/06, 제주국제컨벤션센터(ICCJEJU)) |
| 권호 |
19권 2호 |
| 발표분야 |
환경에너지_포스터 |
| 제목 |
Electro-reduction of Allyl Chloride by Cobalt (I) in 1-butyl-3-methyl imidazolium hexafluorophosphate at various temperatures |
| 초록 |
Cyclic voltammetric investigations were carried out with Co(II) dissolved in [bmim]PF6. The CV profiles have indicated that Co(II) undergoes facile oxidation and reduction in both the anodic and cathodic potential regions. As a model pollutant allyl chloride was taken to study the effect of Co(II) catalyzed reduction in the cathodic sweep. It was found that allyl chloride was found to undergo reduction catalytically in the presence of Co(II) ion. The diffusion coefficient of Co(II) in [bmim]PF6 found to range between 0.84 x 10-7 to 11.2 x 10-7 cm2/s in the temperature range 25 - 80 °C. The extent of allyl chloride reduction was found by potentiostatic electrolysis and the product formed was analyzed by Fourier Transform Infrared Spectroscopy (FTIR). The electrochemical parameters for the reduction of allyl chloride are calculated and discussed. |
| 저자 |
문일식, SUBRAMANIAN BALAJI, Kannan Karunakaran
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| 소속 |
순천대 |
| 키워드 |
Imidazolium hexafluorophosphate; CoCl2; Cyclic voltammetry; Allyl Chloride reduction
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| E-Mail |
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