| 학회 | 한국고분자학회 |
| 학술대회 | 2004년 가을 (10/08 ~ 10/09, 경북대학교) |
| 권호 | 29권 2호, p.542 |
| 발표분야 | 복합재료 |
| 제목 | Synthesis and Properties of Polyamide66/Clay Nanocomposites via Melt Intercalation. |
| 초록 | Polyamide66(PA66) is a kind of important engineering plastic. Despite polyamide6 and polyamide12/clay nanocomposites have been investigated, there are few papers on PA66/clay nanocomposites. Inspired by epoxide compound as the partially cross-linked agent of polyamide, we want to prepare the co-intercalation clay which absorbing epoxide compound between the silicate layers. It might be expected that the strong interaction between epoxy groups confined in the layers and amide groups of PA66. In this study, we would like to describe the preparation of PA66/clay nanocomposites(PA66CN) via melt intercalation by using a new kind of organophilic montmorillonite through co-intercalation of epoxy resin and alkylammonium into Na-montmorillonite and some basic properties will be discussed. In our present study, the chain-extended organifier having amide group and functional end group was synthesized by two step method. First, carboxyl-terminated PTMG was prepared. Second, the organifier was synthesized by dropping 1 equiv of diamino-N-methyl dipropylamine in 2 equiv of carboxylated PTMG. |
| 저자 | 박민규1, 최우진2, Sriram1, 김성철3 |
| 소속 | 1한국과학기술원, 2LG-Caltex 정유, 3한국과학기술원 기능성고분자신소재연구센터 |
| 키워드 | Polyamide66; Polyamide66/Clay Nanocomposite; Melt intercalation; Co-intercalation |
