화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2007년 가을 (10/11 ~ 10/12, 일산킨텍스)
권호 32권 2호
발표분야 기능성 고분자
제목 Electro-optical Properties of Novel Fluorene-based Functional Polymers via “Click Chemistry”
초록 Triazole formation by 1,3-dipolar cycloaddition reactions, “click chemistry” has been used to synthesize new fluorene-based fnctional polymers. The photo-physical and conductive properties as well as the morphology of these polymers in the solid state were measured. The weight-average molecular weights (Mw) of these polymers were in the reasonable range of (33-8.1×103 ) with PDI range 2.41-1.38 and were completely soluble in common organic solvents. The glass transition temperature of the polymers is in the range of 144-2210C. Both UV-visible and photoluminescence spectra were indicated that all polymers had green emission. From cyclic voltamertric analysis we could able to say that these polymers might be useful as conductive materials.
저자 카림1, 이재욱2, 제갈영순3, 조영래1, 진성호1
소속 1부산대, 2동아대, 3경일대
키워드 click chemisrty; fluorene-based polymers; eletro-optical properties
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