| 학회 |
한국공업화학회 |
| 학술대회 |
2020년 가을 (10/28 ~ 10/30, 광주 김대중컨벤션센터(Kimdaejung Convention Center)) |
| 권호 |
24권 1호 |
| 발표분야 |
포스터-촉매 |
| 제목 |
Sonochemical synthesis of aluminum fumarate metal-organic framework for CO2 cycloaddition to epichlorohydrin |
| 초록 |
Aluminum fumarate was tested as a catalyst for CO2 cycloaddition to epichlorohydrin under solvent-free reaction conditions. It was synthesized hydrothermally via a sonochemical route (Al fumarate-(S)), which exhibited a higher catalytic activity than Al fumarate synthesized by a conventional method owing to the higher number of Lewis acid sites formed in Al fumarate-(S). The CO2 uptake of Al fumarate-(S) was high: 269 mg g-1 at 25 °C and 10 bar. High conversion (96%) of epichlorohydrin with excellent selectivity (97%) to cyclic carbonate was obtained at 50 °C and 10 bar CO2 after 6 h of reaction. The kinetic analysis of the reaction confirmed an approximately 1st order dependence on the epichlorohydrin concentration and CO2 pressure. The recovered Al fumarate-(S) catalyst, however, showed a steady decline in catalytic activity during the recycling runs. The deactivation was monitored by N2 adsorption-desorption isotherms and spectroscopic analyses. |
| 저자 |
김현섭1, 임용현1, 김도희1, 안화승2
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| 소속 |
1서울대, 2인하대 |
| 키워드 |
Metal-organic frameworks; Aluminum fumarate; Sonochemical synthesis; CO2 cycloaddition
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| E-Mail |
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