| 학회 |
한국고분자학회 |
| 학술대회 |
2014년 봄 (04/10 ~ 04/11, 대전 컨벤션센터) |
| 권호 |
39권 1호 |
| 발표분야 |
고분자가공/복합재료- 미래 자동차용 고분자소재 최신기술 동향 |
| 제목 |
Semiconductor wrapped by amine functionalized graphene as effective photoconversion of CO2 with high capacity for CO2 capture |
| 초록 |
The human have been faced the two severe crisis of global warming and shortage of fossil fuel due to dramtic increase in comsumed energy. So, the photoreduction of CO2 to valuable chemical fuel has been made attraction to consume the CO2 and produce the sustainable and clean energy due to only using sun light and water. To increase the efficiency of photocatalyst, the graphene has been utilized in various semiconductor composites owing to the ability for efficient electron separation. In this research, we merge the CO2 capture system to CO2 conversion system to increase the reactive sites for CO2. The amine group was utilized to chemisorption of CO2 in mild condition and also easily reacts with hydroxide and carboxyl groups. Thus, we make the semiconductor wrapped by amine functionalized graphene followed by substitution for amine group on graphene surfaces. This photocatalyst system shows the improved CO2 affinities and high conversion rate for CO2 without any noble metals. |
| 저자 |
조경민1, 김경환2, 정희태2
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| 소속 |
1한국과학기술원, 2KAIST |
| 키워드 |
photocatalyst; CO2 photoconversion; graphene;
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| E-Mail |
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