학회 |
한국고분자학회 |
학술대회 |
2011년 가을 (10/06 ~ 10/07, 김대중 컨벤션센터) |
권호 |
36권 2호 |
발표분야 |
고분자합성-구조제어중합 |
제목 |
Ethylene Tetramerization with Diphosphinoamine Ligands Tethering Pendant Amine Donors |
초록 |
A series of diphosphinoamine ligands bearing amine groups were prepared. Metallation of the ligands afforded the corresponding chromium complexes for ethylene tetramerization, which were used in ethylene oligomerizaton in the presence of MAO. It was observed that the structure of the ligands and the reaction conditions had significant influences on catalytic activities and 1-alkene selectivities. |
저자 |
사석필1, 이승민1, 이용호2, 조민석2, 김상율1
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소속 |
1KAIST, 2LG화학 |
키워드 |
ethylene; oligomerization; tetramerization; 1-octene
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E-Mail |
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