화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2004년 가을 (10/08 ~ 10/09, 경북대학교)
권호 29권 2호, p.537
발표분야 고분자 가공/블렌드
제목 Microparticle formation of PEO-PPO-PEO block copolymer using carbon dioxide as a supercritical antisolvent.
초록 Carbon dioxide has been promoted as a sustainable solvent, as CO2 is non-flammable, relatively low toxic and naturally abundant. Micronization of the poly(ethylene oxide)-poly(propylene oxide)-poly(ethylene oxide) (PEO-PPO-PEO) block copolymers was successfully performed using carbon dioxide as a supercritical antisolvent. PEO-PPO-PEO microparticle showed attractive capability to absorb hydrophilic compounds. Methanol, ethanol and acetone were included as solvents for PEO-PPO-PEO to study solvent effects on particle morphologies. The effects of pressure, temperature and PEO-PPO-PEO concentration on particle morphologies were also investigated.. Scanning electron microscopy (SEM) and laser particle size analyzer were used to characterize particle size and morphologies.
저자 이종우, 심진기, 조계민
소속 한국생산기술(연)
키워드 PEO-PPO-PEO; Supercritical antisolvent precipitation
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