화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2010년 가을 (10/07 ~ 10/08, 대구 EXCO)
권호 35권 2호
발표분야 분자전자소재 및 소자
제목 Thermally Cross-linkable Hole injection/transporting Materials Based on 10H-alkylphenothiazine Oligomers for Multi-layer Structured Polymer Light Emitting Diodes
초록 The materials derived from 10-alkylphenothiazine have good hole injecting/transporting properties due to their high-lying HOMO energy level. In order to fabricate multi-layer structured polymer light emitting diodes (PLEDs), the hole injecting/transporting materials should have solvent resistance. We synthesized thermally cross-linkable 10H-alkylphenothiazine (PT) oligomers with thermally cross-linkable MA or VB unit. The absorbance of UV-Vis spectra of thin film of thermally cross-linked PT oligomers (cross-PT) on the glass substrate and washed thermally cross-PT film with methylene chloride (MC) were almost same. The HOMO energy levels and electrochemical stability of cross-PT oligomers were figured out from the cyclic voltammetry (CV). Bilayer structured polymer light-emitting diode (PLED) was fabricated and characterized. In this presentation, we will report synthesis, optical, electrochemical, and electroluminescent properties.
저자 조미영, 박상준, 박정배, 김주현
소속 부경대
키워드 thermal crosslinking; 10-alkylphenothiazine; hole injecting/transporting material; PLED
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