초록 |
Phase behavior data are reported for CO2 + 2-phenoxyethyl acrylate systems at 40 ~ 120 oC and pressures up to 311 bar and for CO2 + 2-phenoxyethyl methacrylate systems at 40, 60, 80, 100 and 120 oC and pressures up to 305 bar. The solubility of monomers for the CO2 + 2-phenoxyethyl acrylate and CO2 + 2-phenoxyethyl methacrylate systems increase as the temperature increases at constant pressure. The CO2 + 2-phenoxyethyl acrylate and CO2 + 2-phenoxyethyl methacrylate systems exhibit type-I phase behavior. The experimental results for CO2 + 2-phenoxyethyl acrylate and CO2 + 2-phenoxyethyl methacrylate systems were correlated with Peng-Robinson equation of state using a van der Waals one-fluid mixing rule. |