화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2003년 가을 (10/10 ~ 10/11, 부경대학교)
권호 28권 2호, p.187
발표분야 분자전자 부문위원회
제목 New Colorimetric and Fluorometric Chemosensor Based on Polybenzoxazole Derivative
초록 Selective binding of chemical ionic species by molecular recognition can lead to host environmental perturbation. Fluoroionophores transduce ion concentrations into measurable signals and thus the interest on such fluoroionophores are increasing substantially. Recently specific detection of inorganic anions and metal cations has been focused because of their important roles in biological, industrial, or environmental process. A new fluorescent chemosensor, polyhydroxybenzoxazole, was synthesized via Suzuki coupling reaction. The polymer is attractive because of the possible use of their unique excited state intramolecular proton transfer (ESIPT) property. Accordingly, we studied the optical properties of the corresponding polymer. Particularly the ability to coordinate to ions in solutions was investigated and fluoride anion was found to be most effective in controlling optical behavior of the synthesized polymer.
저자 이진구, 박원호, 이택승
소속 충남대
키워드 chemosensor; ESIPT
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