화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2010년 가을 (10/07 ~ 10/08, 대구 EXCO)
권호 35권 2호
발표분야 기능성 고분자
제목 High Performance Transparent Conductive Film of Rheologically-derived Reduced Graphene Oxide by Shear Stress
초록 In this work, we produced large area graphene oxide (GO) sheets by inducing of shear stress and obtained high quality reduced graphene oxide (RGO) sheets without post annealing process, which is described as rheologically-derived RGO. The large area GO sheets are generated by homogenizer in aqueous solution due to slip of GO to the in-plane direction during exfoliation process, in contrast to a conventional sonication method. The effects of chemical reduction at mild conditions demonstrate that the formation of structural defects during exfoliation process can affects the RGO properties. In Raman spectra, the ID/IG ratio of homogenizer-used RGO (HRGO) was increased more than that of sonicated-RGO (SRGO) because of large amount of the ordered sixfold rings on the basal plane. The enhanced sheet resistance of HRGO shows 2.2 k/sq at 80% transmittance. The effective exfoliation method has great potential for the application of high performance RGO-TCFs.
저자 김성훈, 정승열, 이건웅, 한중탁, 정희진
소속 한국전기(연)
키워드 Reduced graphene oxide; shear stress; homogenizer; exfoliation; structural defects
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