화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2007년 봄 (04/12 ~ 04/13, 제주 ICC)
권호 32권 1호
발표분야 블록공중합체를 이용한 신기능 나노물질 개발 및 분석
제목 Molecular interpretation of scattering behavior of styrenic block copolymers
초록 Scattering behavior of some block copolymers containing polystyrene is studied by small angle neutron scattering (SANS). The absolute scattering intensities and the resultant correlation lengths for the disordered samples are obtained as a function of temperature and pressure. The experimental scattering behavior is then analyzed by using random-phase approximation (RPA) analysis in connection with a molecular model for perturbed hard chains. Requisite molecular parameters are used to predict the scattering properties for the copolymers, which are compared with those measured by SANS. Effective Flory-type interaction is obtained and discussed with regard to its role in the scattering behavior for the copolymers.
저자 이인호1, 이강영1, 이동현2, 류두열3, 김진곤2, 조준한1
소속 1단국대, 2포항공대 화공, 3연세대 화공
키워드 블록공중합체; 소각중성자산란; 분자이론
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