학회 |
한국공업화학회 |
학술대회 |
2016년 가을 (10/26 ~ 10/28, 제주국제컨벤션센터(ICCJEJU)) |
권호 |
20권 2호 |
발표분야 |
에너지저장변환_포스터 |
제목 |
Preparation of Anion Exchange Membrane based on Poly(phenylene Oxide) for Vanadium Redox Flow Battery |
초록 |
A polyphenylene oxide (PPO)-based anion exchange membrane based on the functionalization of bromomethylated PPO using 1-methylimdazole was fabricated for vanadium redox flow application. The imidazolium-bromomethylated PPO (Im-bPPO) showed lower permeability of VO2+ ions (2.9×10-14 m2/sec), compared to Nafion 212 (2.3×10-12 m2/sec) and FAP-450 (7.9×10-14 m2/sec). Even though the Im-bPPO membrane has higher permeability, the energy efficiency of the VRFB with the Im-bPPO membrane was slightly lower than that of Nafion and FAP-450. The Im-bPPO membrane exhibits good voltage efficiency compared to FAP-450 and Nafion 212 because of its better ion conductivity. The Im-bPPO membrane showed up good performance, but a decline in performance at later cycles was observed. |
저자 |
임민화, 박미정, 문건오, 노현준, Pham Tan Thong, SADHASIVAM THANGARASU, 정호영
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소속 |
전남대 |
키워드 |
Vanadium Redox Flow Battery; Anion Exchange Membrane; Poly(phenylene oxide) (PPO)
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E-Mail |
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