화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2017년 가을 (10/25 ~ 10/27, 대전컨벤션센터)
권호 23권 2호, p.1456
발표분야 고분자
제목 Highly Permeable Super Absorbent Polymer via Pickering poly-HIPE Template
초록 In this paper, super absorbent polymer has high porosity, high permeability, fast swelling rate which is fabricated via Pickering high internal phase emulsion template was investigated to resolve 'gel-blocking' problem occurred existing sieved particle form polymers. This work presented open porous structure fabricated only with hydrophilic nanoparticles and also very stable Pickering emulsion made with depletants and polymerizable contents in continuous phase by depletion attraction strategy. Number of pore throats and permeability of bulk porous structure are actually affected by internal volume fraction. When 0.80 of internal volume fraction of oil phase, polymerized porous super absorbent polymer was impermeable to aqueous fluids. But after increasing volume fraction of oil, increased number of open pores were observed by SEM also polymer permeable to aqueous fluids. Also swelling rates, pore sizes varied with internal volume fraction were investigated.
저자 신희웅, 김수빈, 최시영
소속 한국과학기술원
키워드 기능성고분자
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