| 학회 |
한국고분자학회 |
| 학술대회 |
2015년 봄 (04/08 ~ 04/10, 대전컨벤션센터) |
| 권호 |
40권 1호 |
| 발표분야 |
고분자합성 |
| 제목 |
Base-Free Suzuki Polymerization with Fluoride-salt Mediated for Siloxane-Based Hybrid Semiconducting Polymers |
| 초록 |
In this report, a practical variation of the Suzuki polymerization to generate semiconducting polymeric hybrids based on siloxane units, which proceeds under essentially non-basic conditions, is presented and optimized. This method can be used to generate solution-processable poly(diketopyrrolopyrrole-alt-benzothiadiazole) (PDPPBT-Si) polymer consisting of the hybrid siloxane substituents, which could not be made using conventional methods. PDPPBT-Si exhibits excellent ambipolar transistor performance with well-balanced hole and electron FET mobilities. The siloxane-containing DPP-thiophene polymer classes (PDPP3T-Si and PDPP4T-Si), synthesized via this method, exhibit high hole mobility of up to 1.29 cm2 V-1 s-1. This synthetic approach should provide access to a variety of novel siloxane-containing conjugated semiconductor classes via a selection of aryldihalides and aryldiboronic acids/esters. |
| 저자 |
이상면1, 이정훈1, 한아름1, 유도혁1, 오준학2, 양창덕1
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| 소속 |
1UNIST, 2POSTECH |
| 키워드 |
base-free Suzuki polycondensation; microwave-assisted Suzuki polymerization; siloxane-based hybrid side chain; diketopyrrolopyrrole; organic field-effect transistor
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| E-Mail |
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