| 학회 |
한국고분자학회 |
| 학술대회 |
2009년 가을 (10/08 ~ 10/09, 광주과학기술원 오룡관) |
| 권호 |
34권 2호 |
| 발표분야 |
고분자 구조 및 물성 |
| 제목 |
Highly-Ordered Bilayer Structures of Gold(I)-Alkanethiolates Having Two Types of Alkyl Groups |
| 초록 |
The luminescent gold(I)-alkanethiolates containing two types of alkyl groups, Au(I)-(SR)x(SR’)ys, were synthesized by mixing HAuCl4 with two n-alkanethiols in tetrahydrofuran. Au(I)-(SR)x(SR’)ys have highly-order bilayer structures and the dominant conformation of the alkyl groups were found to be all-trans from X-ray diffraction and FT-IR spectroscopy studies. The gold nanoparticles stabilized by two types of alkanethiolates could be prepared by reducing the Au(I)-(SR)x(SR’)ys using tetrabutylammonium borohydride (TBABH) as a reducing agent. Elemental analysis results of Au(I)-(SR)x(SR’)ys and gold nanoparticles prepared from Au(I)-(SR)x(SR’)ys indicated that that the longer alkanethiols are more reactive for the formation of Au(I)-(SR)x(SR’)ys and also the longer alkylthiolate are preferentially absorbed on the gold particles compared with the shorter ones. |
| 저자 |
차상호, 김기현, 이원기, 이종찬
|
| 소속 |
서울대 |
| 키워드 |
gold complexes; alkanethiolates; lamellar; gold nanoparticles
|
| E-Mail |
|
