| 학회 |
한국고분자학회 |
| 학술대회 |
2004년 봄 (04/09 ~ 04/10, 고려대학교) |
| 권호 |
29권 1호, p.97 |
| 발표분야 |
고분자 합성 |
| 제목 |
Novel Ni(Ⅱ)-Based Catalysts for the Polymerization of Ethylene |
| 초록 |
In 1995, brookhart group have reported the polymerization of ethylene by using cationic Ni(Ⅱ) α-diimine complexes. We were interested in exploring and synthesizing some new ligands in order to develop new late-transition metal complexes for olefin polymerization catalysis. Here we reported the synthesis of new ligands modified with α-diimine based on the above-mentioned catalysts. The new catalysts were observed high activity for the ethylene polymerization. The influence of the ligand substituents on the catalystic activity has been investigated. Also we will carry out the ethylene polymerization at various temperatures and MAO concentrations. |
| 저자 |
손기완1, 하창식2, 김일1
|
| 소속 |
1부산대, 2초미세화학공정시스템연구센터 |
| 키워드 |
the Polymerization of Ethylene |
| E-Mail |
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